1\documentclass{article} 2 3\usepackage[latin1]{inputenc} 4\usepackage{tikz} 5 6\setlength{\pdfpagewidth}{25.7cm} 7\setlength{\pdfpageheight}{6.1cm} 8%\setlength{\pdfvorigin}{25.4mm} 9 10%\setlength{\textwidth}{24.2cm} 11%\setlength{\textheight}{18cm} 12%\setlength{\evensidemargin}{-2.7cm} 13\setlength{\oddsidemargin}{-3.1cm} 14\setlength{\topmargin}{-4.45cm} 15\setlength{\headheight}{2cm} 16\setlength{\headsep}{0cm} 17 18\usetikzlibrary{shapes,arrows,shapes.geometric,calc,patterns} 19 20\usepackage{amsmath} 21\usepackage{amssymb} 22\usepackage{amsthm} 23\usepackage{color} 24 25\begin{document} 26 27\pagestyle{empty} 28 29\tikzstyle{block}=[color=black, fill=black!15, rectangle, draw, sharp corners, very thin, node distance=0mm] 30\tikzstyle{arrow}=[draw, -latex'] 31 32\begin{tikzpicture}[scale=1, auto] 33 34% zeroth order Cartesian multipole moment 35\node[block, minimum width=2mm, minimum height=2mm] at (1mm,1mm){}; 36\node[block, minimum width=6mm, minimum height=2mm] at (5mm,1mm){}; 37\node[block, minimum width=12mm, minimum height=2mm] at (14mm,1mm){}; 38\node[block, minimum width=20mm, minimum height=2mm] at (30mm,1mm){}; 39\node[block, minimum width=30mm, minimum height=2mm] at (55mm,1mm){}; 40\node[block, minimum width=42mm, minimum height=2mm] at (91mm,1mm){}; 41\node[block, minimum width=56mm, minimum height=2mm] at (140mm,1mm){}; 42\node[block, minimum width=72mm, minimum height=2mm] at (204mm,1mm){}; 43 44% first order Cartesian multipole moment 45\node[block, minimum width=2mm, minimum height=6mm] at (1mm,5mm){}; 46\node[block, minimum width=6mm, minimum height=6mm] at (5mm,5mm){}; 47\node[block, minimum width=12mm, minimum height=6mm] at (14mm,5mm){}; 48\node[block, minimum width=20mm, minimum height=6mm] at (30mm,5mm){}; 49\node[block, minimum width=30mm, minimum height=6mm] at (55mm,5mm){}; 50\node[block, minimum width=42mm, minimum height=6mm] at (91mm,5mm){}; 51\node[block, minimum width=56mm, minimum height=6mm] at (140mm,5mm){}; 52 53% second order Cartesian multipole moment 54\node[block, minimum width=6mm, minimum height=12mm] at (5mm,14mm){}; 55\node[block, fill=black!30, minimum width=12mm, minimum height=12mm] at (14mm,14mm){}; 56\node[block, fill=black!30, minimum width=20mm, minimum height=12mm] at (30mm,14mm){}; 57\node[block, fill=black!30, minimum width=30mm, minimum height=12mm] at (55mm,14mm){}; 58\node[block, minimum width=42mm, minimum height=12mm] at (91mm,14mm){}; 59 60% third order Cartesian multipole moment 61\node[block, fill=black!30, minimum width=12mm, minimum height=20mm] at (14mm,30mm){}; 62\node[block, fill=black!30, minimum width=20mm, minimum height=20mm] at (30mm,30mm){}; 63\node[block, fill=black!30, minimum width=30mm, minimum height=20mm] at (55mm,30mm){}; 64 65% axis of HGTOs 66\node at (1mm,-2mm) {$s$}; 67\node at (5mm,-2mm) {$p$}; 68\node at (14mm,-2mm) {$d$}; 69\node at (30mm,-2mm) {$f$}; 70\node at (55mm,-2mm) {$g$}; 71\node at (91mm,-2mm) {$h$}; 72\node at (140mm,-2mm) {$i$}; 73\node at (204mm,-2mm) {$j$}; 74\path[arrow](-0.15mm,-0.15mm)--node[yshift=-10mm] % 75 {$\boldsymbol{l}_{\kappa}$ ($\min=2$, $\max=4$)}(246mm,-0.15mm); 76 77% axis of Cartesian multipole moments 78\node at (-2mm,1mm) {$s$}; 79\node at (-2mm,5mm) {$p$}; 80\node at (-2mm,14mm) {$d$}; 81\node at (-2mm,30mm) {$f$}; 82\path[arrow](-0.15mm,-0.15mm)--node[rotate=90, xshift=20mm, yshift=7mm] % 83 {$\boldsymbol{N}_{1}$ ($\min=2$, $\max=3$)}(-0.15mm,50mm); 84 85\end{tikzpicture} 86 87\end{document} 88