1&GLOBAL 2 PROGRAM_NAME ATOM 3&END GLOBAL 4&ATOM 5 ELEMENT O 6 7 RUN_TYPE PSEUDOPOTENTIAL_OPTIMIZATION 8 9 ELECTRON_CONFIGURATION [He] 2s2 2p4 10 CORE [He] 11 MAX_ANGULAR_MOMENTUM 2 12 13 COULOMB_INTEGRALS ANALYTIC 14 EXCHANGE_INTEGRALS ANALYTIC 15 16 &METHOD 17 METHOD_TYPE KOHN-SHAM 18 RELATIVISTIC DKH(2) 19 &XC 20 &XC_FUNCTIONAL 21 &BECKE97 22 PARAMETRIZATION B97GRIMME 23 &END 24 &END XC_FUNCTIONAL 25 &END XC 26 &END METHOD 27 &OPTIMIZATION 28 EPS_SCF 1.e-10 29 &END 30 &PRINT 31 &BASIS_SET 32 &END 33 &END 34 35 &AE_BASIS 36 BASIS_TYPE GEOMETRICAL_GTO 37 GRID_POINTS 100 38 &END AE_BASIS 39 &PP_BASIS 40 BASIS_TYPE GEOMETRICAL_GTO 41 &END PP_BASIS 42 &POTENTIAL 43 PSEUDO_TYPE GTH 44 >H_POTENTIAL 45 2 4 0 0 46 0.241474531885 2 -16.691805741058 2.494605958440 47 1 48 0.220838245905 1 18.355844903927 49 &END 50 &END POTENTIAL 51 52 &POWELL 53 ! ACCURACY 1.e-12 54 ACCURACY 1.e-0 55 STEP_SIZE 0.25 56 WEIGHT_PSIR0 0.1 57 &END 58&END ATOM 59