1*********************************************************** 2*********************************************************** 3 4 This calculation was performed by OpenMX Ver. 3.7.33 5 using 16 MPI processes and 1 OpenMP threads. 6 7 Mon Mar 28 15:30:24 2016 8 9*********************************************************** 10*********************************************************** 11 12# 13# File Name 14# 15 16System.CurrrentDirectory ./ # default=./ 17System.Name d-H2O_RF 18level.of.stdout 1 # default=1 (1-3) 19level.of.fileout 0 # default=1 (1-3) 20 21# 22# Definition of Atomic Species 23# 24 25Species.Number 2 26<Definition.of.Atomic.Species 27 H H7.0-s2p1 H_PBE13 28 O O7.0-s2p2d1 O_PBE13 29Definition.of.Atomic.Species> 30 31# 32# Atoms 33# 34 35Atoms.Number 6 36Atoms.SpeciesAndCoordinates.Unit Ang # Ang|AU 37<Atoms.SpeciesAndCoordinates # Unit=Ang. 38 1 O 0.000 0.000 0.000 3.0 3.0 39 2 H 0.757 0.586 0.000 0.5 0.5 40 3 H -0.757 0.586 0.000 0.5 0.5 41 4 O 0.000 5.000 0.000 3.0 3.0 42 5 H 0.000 5.586 0.757 0.5 0.5 43 6 H 0.000 5.586 -0.757 0.5 0.5 44Atoms.SpeciesAndCoordinates> 45Atoms.UnitVectors.Unit Ang # Ang|AU 46#<Atoms.UnitVectors 47# 8.0 0.0 0.0 48# 0.0 8.0 0.0 49# 0.0 0.0 8.0 50#Atoms.UnitVectors> 51 52# 53# SCF or Electronic System 54# 55 56scf.XcType GGA-PBE # LDA|LSDA-CA|LSDA-PW 57scf.SpinPolarization off # on|off|nc 58scf.ElectronicTemperature 100.0 # default=300 (K) 59scf.energycutoff 180.0 # default=150 (Ry) 60scf.maxIter 60 # default=40 61scf.EigenvalueSolver cluster # Recursion|Cluster|Band 62scf.Kgrid 4 4 4 # means 4x4x4 63scf.Mixing.Type rmm-diis # Simple|Rmm-Diis|Gr-Pulay 64scf.Init.Mixing.Weight 0.10 # default=0.30 65scf.Min.Mixing.Weight 0.001 # default=0.001 66scf.Max.Mixing.Weight 0.400 # default=0.40 67scf.Mixing.History 7 # default=5 68scf.Mixing.StartPulay 10 # default=6 69scf.criterion 1.0e-8 # default=1.0e-6 (Hartree) 70 71# 72# MD or Geometry Optimization 73# 74 75MD.Type RF # Nomd|Opt|DIIS|NVE|NVT_VS|NVT_NH 76MD.Opt.DIIS.History 3 # default=3 77MD.Opt.StartDIIS 12 # default=5 78MD.Opt.EveryDIIS 10000 # default=10 79MD.maxIter 200 # default=1xsx 80MD.TimeStep 1.0 # default=0.5 (fs) 81MD.Opt.criterion 1.0e-4 # default=1.0e-4 (Hartree/bohr) 82 83 84*********************************************************** 85*********************************************************** 86 87 Required cutoff energy (Ryd) for 3D-grids = 180.0000 88 Used cutoff energy (Ryd) for 3D-grids = 180.0010, 180.0010, 180.0010 89 Num. of grids of a-, b-, and c-axes = 80, 120, 80 90 91 Num.Grid1. 80 92 Num.Grid2. 120 93 Num.Grid3. 80 94 95 96 Cell_Volume = 9860.489190752132 (Bohr^3) 97 GridVol = 0.012839178634 (Bohr^3) 98 Cell vectors (bohr) of the grid cell (gtv) 99 gtv_a = 0.234159840592, 0.000000000000, 0.000000000000 100 gtv_b = 0.000000000000, 0.234159840592, 0.000000000000 101 gtv_c = 0.000000000000, 0.000000000000, 0.234159840592 102 |gtv_a| = 0.234159840592 103 |gtv_b| = 0.234159840592 104 |gtv_c| = 0.234159840592 105 106*********************************************************** 107*********************************************************** 108 109 110*********************************************************** 111*********************************************************** 112 SCF history at MD= 1 113*********************************************************** 114*********************************************************** 115 116 SCF= 1 NormRD= 1.000000000000 Uele= -10.715163052360 117 SCF= 2 NormRD= 1.864285527445 Uele= -10.582197072334 118 SCF= 3 NormRD= 1.772020507980 Uele= -9.301252503417 119 SCF= 4 NormRD= 0.815622728981 Uele= -8.587375618065 120 SCF= 5 NormRD= 0.254266903914 Uele= -8.359846314921 121 SCF= 6 NormRD= 0.035707839514 Uele= -8.123527078300 122 SCF= 7 NormRD= 0.045120836498 Uele= -7.992611661461 123 SCF= 8 NormRD= 0.028393703641 Uele= -8.051024911193 124 SCF= 9 NormRD= 0.015270073265 Uele= -8.112691530344 125 SCF= 10 NormRD= 0.011671193927 Uele= -8.147977962476 126 SCF= 11 NormRD= 0.008459623653 Uele= -8.154793304849 127 SCF= 12 NormRD= 0.006414107987 Uele= -8.142065797513 128 SCF= 13 NormRD= 0.000182054814 Uele= -8.160299983188 129 SCF= 14 NormRD= 0.000020871978 Uele= -8.160170118031 130 SCF= 15 NormRD= 0.000002517078 Uele= -8.160109208573 131 SCF= 16 NormRD= 0.000002097023 Uele= -8.160111018421 132 SCF= 17 NormRD= 0.000000030454 Uele= -8.160112217565 133 SCF= 18 NormRD= 0.000000001542 Uele= -8.160112308080 134 SCF= 19 NormRD= 0.000000000356 Uele= -8.160112307016 135 136******************************************************* 137 Total energy (Hartree) at MD = 1 138******************************************************* 139 140 Uele. -8.160112307016 141 142 Ukin. 25.837620655361 143 UH0. -46.901086979187 144 UH1. 0.101859497978 145 Una. -32.435347721682 146 Unl. 6.918729839072 147 Uxc0. -4.599076856229 148 Uxc1. -4.599076856229 149 Ucore. 20.734095958843 150 Uhub. 0.000000000000 151 Ucs. 0.000000000000 152 Uzs. 0.000000000000 153 Uzo. 0.000000000000 154 Uef. 0.000000000000 155 UvdW 0.000000000000 156 Utot. -34.942282462073 157 158 Note: 159 160 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 161 162 Uene: band energy 163 Ukin: kinetic energy 164 UH0: electric part of screened Coulomb energy 165 UH1: difference electron-electron Coulomb energy 166 Una: neutral atom potential energy 167 Unl: non-local potential energy 168 Uxc0: exchange-correlation energy for alpha spin 169 Uxc1: exchange-correlation energy for beta spin 170 Ucore: core-core Coulomb energy 171 Uhub: LDA+U energy 172 Ucs: constraint energy for spin orientation 173 Uzs: Zeeman term for spin magnetic moment 174 Uzo: Zeeman term for orbital magnetic moment 175 Uef: electric energy by electric field 176 UvdW: semi-empirical vdW energy 177 178 (see also PRB 72, 045121(2005) for the energy contributions) 179 180 181 182 Chemical potential (Hartree) -0.234375000000 183 184*********************************************************** 185*********************************************************** 186 SCF history at MD= 2 187*********************************************************** 188*********************************************************** 189 190 SCF= 1 NormRD= 1.000000000000 Uele= -8.041849419537 191 SCF= 2 NormRD= 0.036220443493 Uele= -8.218501655883 192 SCF= 3 NormRD= 0.008765101770 Uele= -8.094915222979 193 SCF= 4 NormRD= 0.001914814584 Uele= -8.112674525016 194 SCF= 5 NormRD= 0.001952516902 Uele= -8.102016502712 195 SCF= 6 NormRD= 0.000090366531 Uele= -8.108445813634 196 SCF= 7 NormRD= 0.000015046662 Uele= -8.108226603617 197 SCF= 8 NormRD= 0.000006911343 Uele= -8.108208789789 198 SCF= 9 NormRD= 0.000000176048 Uele= -8.108196746716 199 SCF= 10 NormRD= 0.000000007191 Uele= -8.108196289559 200 SCF= 11 NormRD= 0.000000002730 Uele= -8.108196299850 201 SCF= 12 NormRD= 0.000000000147 Uele= -8.108196303646 202 203******************************************************* 204 Total energy (Hartree) at MD = 2 205******************************************************* 206 207 Uele. -8.108196303646 208 209 Ukin. 25.710181712096 210 UH0. -46.799275036890 211 UH1. 0.098545520963 212 Una. -32.206380932781 213 Unl. 6.905329190024 214 Uxc0. -4.584408664269 215 Uxc1. -4.584408664269 216 Ucore. 20.517474311444 217 Uhub. 0.000000000000 218 Ucs. 0.000000000000 219 Uzs. 0.000000000000 220 Uzo. 0.000000000000 221 Uef. 0.000000000000 222 UvdW 0.000000000000 223 Utot. -34.942942563681 224 225 Note: 226 227 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 228 229 Uene: band energy 230 Ukin: kinetic energy 231 UH0: electric part of screened Coulomb energy 232 UH1: difference electron-electron Coulomb energy 233 Una: neutral atom potential energy 234 Unl: non-local potential energy 235 Uxc0: exchange-correlation energy for alpha spin 236 Uxc1: exchange-correlation energy for beta spin 237 Ucore: core-core Coulomb energy 238 Uhub: LDA+U energy 239 Ucs: constraint energy for spin orientation 240 Uzs: Zeeman term for spin magnetic moment 241 Uzo: Zeeman term for orbital magnetic moment 242 Uef: electric energy by electric field 243 UvdW: semi-empirical vdW energy 244 245 (see also PRB 72, 045121(2005) for the energy contributions) 246 247 248 249 Chemical potential (Hartree) -0.234375000000 250 251*********************************************************** 252*********************************************************** 253 SCF history at MD= 3 254*********************************************************** 255*********************************************************** 256 257 SCF= 1 NormRD= 1.000000000000 Uele= -8.125825277062 258 SCF= 2 NormRD= 0.005404602677 Uele= -8.099450468687 259 SCF= 3 NormRD= 0.001323296168 Uele= -8.117869686117 260 SCF= 4 NormRD= 0.000298928579 Uele= -8.115164956045 261 SCF= 5 NormRD= 0.000289032815 Uele= -8.116732357026 262 SCF= 6 NormRD= 0.000018318283 Uele= -8.115768714434 263 SCF= 7 NormRD= 0.000002930516 Uele= -8.115816175802 264 SCF= 8 NormRD= 0.000000870122 Uele= -8.115819170753 265 SCF= 9 NormRD= 0.000000014160 Uele= -8.115821059398 266 SCF= 10 NormRD= 0.000000001720 Uele= -8.115821094710 267 SCF= 11 NormRD= 0.000000000356 Uele= -8.115821094450 268 269******************************************************* 270 Total energy (Hartree) at MD = 3 271******************************************************* 272 273 Uele. -8.115821094450 274 275 Ukin. 25.728918052732 276 UH0. -46.814562437441 277 UH1. 0.099023565525 278 Una. -32.239889040263 279 Unl. 6.907201509512 280 Uxc0. -4.586572736956 281 Uxc1. -4.586572736956 282 Ucore. 20.549495430389 283 Uhub. 0.000000000000 284 Ucs. 0.000000000000 285 Uzs. 0.000000000000 286 Uzo. 0.000000000000 287 Uef. 0.000000000000 288 UvdW 0.000000000000 289 Utot. -34.942958393457 290 291 Note: 292 293 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 294 295 Uene: band energy 296 Ukin: kinetic energy 297 UH0: electric part of screened Coulomb energy 298 UH1: difference electron-electron Coulomb energy 299 Una: neutral atom potential energy 300 Unl: non-local potential energy 301 Uxc0: exchange-correlation energy for alpha spin 302 Uxc1: exchange-correlation energy for beta spin 303 Ucore: core-core Coulomb energy 304 Uhub: LDA+U energy 305 Ucs: constraint energy for spin orientation 306 Uzs: Zeeman term for spin magnetic moment 307 Uzo: Zeeman term for orbital magnetic moment 308 Uef: electric energy by electric field 309 UvdW: semi-empirical vdW energy 310 311 (see also PRB 72, 045121(2005) for the energy contributions) 312 313 314 315 Chemical potential (Hartree) -0.234375000000 316 317*********************************************************** 318*********************************************************** 319 SCF history at MD= 4 320*********************************************************** 321*********************************************************** 322 323 SCF= 1 NormRD= 1.000000000000 Uele= -8.115012260848 324 SCF= 2 NormRD= 0.000247602619 Uele= -8.114937126925 325 SCF= 3 NormRD= 0.000065291134 Uele= -8.114953587436 326 SCF= 4 NormRD= 0.000015140455 Uele= -8.114961737233 327 SCF= 5 NormRD= 0.000015596973 Uele= -8.114968412303 328 SCF= 6 NormRD= 0.000000885858 Uele= -8.114966272278 329 SCF= 7 NormRD= 0.000000084147 Uele= -8.114966109600 330 SCF= 8 NormRD= 0.000000043737 Uele= -8.114966363725 331 SCF= 9 NormRD= 0.000000002757 Uele= -8.114966250298 332 SCF= 10 NormRD= 0.000000000461 Uele= -8.114966247701 333 334******************************************************* 335 Total energy (Hartree) at MD = 4 336******************************************************* 337 338 Uele. -8.114966247701 339 340 Ukin. 25.726802980308 341 UH0. -46.813129032863 342 UH1. 0.098969327372 343 Una. -32.236091899152 344 Unl. 6.906983053470 345 Uxc0. -4.586328018122 346 Uxc1. -4.586328018122 347 Ucore. 20.546162179222 348 Uhub. 0.000000000000 349 Ucs. 0.000000000000 350 Uzs. 0.000000000000 351 Uzo. 0.000000000000 352 Uef. 0.000000000000 353 UvdW 0.000000000000 354 Utot. -34.942959427886 355 356 Note: 357 358 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 359 360 Uene: band energy 361 Ukin: kinetic energy 362 UH0: electric part of screened Coulomb energy 363 UH1: difference electron-electron Coulomb energy 364 Una: neutral atom potential energy 365 Unl: non-local potential energy 366 Uxc0: exchange-correlation energy for alpha spin 367 Uxc1: exchange-correlation energy for beta spin 368 Ucore: core-core Coulomb energy 369 Uhub: LDA+U energy 370 Ucs: constraint energy for spin orientation 371 Uzs: Zeeman term for spin magnetic moment 372 Uzo: Zeeman term for orbital magnetic moment 373 Uef: electric energy by electric field 374 UvdW: semi-empirical vdW energy 375 376 (see also PRB 72, 045121(2005) for the energy contributions) 377 378 379 380 Chemical potential (Hartree) -0.234375000000 381 382*********************************************************** 383*********************************************************** 384 SCF history at MD= 5 385*********************************************************** 386*********************************************************** 387 388 SCF= 1 NormRD= 1.000000000000 Uele= -8.115078314673 389 SCF= 2 NormRD= 0.000028839448 Uele= -8.115061351521 390 SCF= 3 NormRD= 0.000009048860 Uele= -8.115067217584 391 SCF= 4 NormRD= 0.000002534443 Uele= -8.115067682984 392 SCF= 5 NormRD= 0.000002814284 Uele= -8.115068988590 393 SCF= 6 NormRD= 0.000000185367 Uele= -8.115068466179 394 SCF= 7 NormRD= 0.000000018320 Uele= -8.115068448306 395 SCF= 8 NormRD= 0.000000011035 Uele= -8.115068505764 396 SCF= 9 NormRD= 0.000000000647 Uele= -8.115068476311 397 SCF= 10 NormRD= 0.000000000106 Uele= -8.115068475917 398 399******************************************************* 400 Total energy (Hartree) at MD = 5 401******************************************************* 402 403 Uele. -8.115068475917 404 405 Ukin. 25.727044642780 406 UH0. -46.813619544875 407 UH1. 0.098975399829 408 Una. -32.236516021401 409 Unl. 6.907003964828 410 Uxc0. -4.586355563960 411 Uxc1. -4.586355563960 412 Ucore. 20.546862591221 413 Uhub. 0.000000000000 414 Ucs. 0.000000000000 415 Uzs. 0.000000000000 416 Uzo. 0.000000000000 417 Uef. 0.000000000000 418 UvdW 0.000000000000 419 Utot. -34.942960095538 420 421 Note: 422 423 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 424 425 Uene: band energy 426 Ukin: kinetic energy 427 UH0: electric part of screened Coulomb energy 428 UH1: difference electron-electron Coulomb energy 429 Una: neutral atom potential energy 430 Unl: non-local potential energy 431 Uxc0: exchange-correlation energy for alpha spin 432 Uxc1: exchange-correlation energy for beta spin 433 Ucore: core-core Coulomb energy 434 Uhub: LDA+U energy 435 Ucs: constraint energy for spin orientation 436 Uzs: Zeeman term for spin magnetic moment 437 Uzo: Zeeman term for orbital magnetic moment 438 Uef: electric energy by electric field 439 UvdW: semi-empirical vdW energy 440 441 (see also PRB 72, 045121(2005) for the energy contributions) 442 443 444 445 Chemical potential (Hartree) -0.234375000000 446 447*********************************************************** 448*********************************************************** 449 SCF history at MD= 6 450*********************************************************** 451*********************************************************** 452 453 SCF= 1 NormRD= 1.000000000000 Uele= -8.115018906451 454 SCF= 2 NormRD= 0.000016435858 Uele= -8.115059725700 455 SCF= 3 NormRD= 0.000005994792 Uele= -8.115024774314 456 SCF= 4 NormRD= 0.000002500867 Uele= -8.115031111829 457 SCF= 5 NormRD= 0.000002592836 Uele= -8.115023630151 458 SCF= 6 NormRD= 0.000000138947 Uele= -8.115030777839 459 SCF= 7 NormRD= 0.000000011920 Uele= -8.115030512105 460 SCF= 8 NormRD= 0.000000011783 Uele= -8.115030494190 461 SCF= 9 NormRD= 0.000000001908 Uele= -8.115030498704 462 463******************************************************* 464 Total energy (Hartree) at MD = 6 465******************************************************* 466 467 Uele. -8.115030498704 468 469 Ukin. 25.726925461587 470 UH0. -46.814303947210 471 UH1. 0.098972104786 472 Una. -32.236289364816 473 Unl. 6.906987263293 474 Uxc0. -4.586341494005 475 Uxc1. -4.586341494005 476 Ucore. 20.547429777971 477 Uhub. 0.000000000000 478 Ucs. 0.000000000000 479 Uzs. 0.000000000000 480 Uzo. 0.000000000000 481 Uef. 0.000000000000 482 UvdW 0.000000000000 483 Utot. -34.942961692400 484 485 Note: 486 487 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 488 489 Uene: band energy 490 Ukin: kinetic energy 491 UH0: electric part of screened Coulomb energy 492 UH1: difference electron-electron Coulomb energy 493 Una: neutral atom potential energy 494 Unl: non-local potential energy 495 Uxc0: exchange-correlation energy for alpha spin 496 Uxc1: exchange-correlation energy for beta spin 497 Ucore: core-core Coulomb energy 498 Uhub: LDA+U energy 499 Ucs: constraint energy for spin orientation 500 Uzs: Zeeman term for spin magnetic moment 501 Uzo: Zeeman term for orbital magnetic moment 502 Uef: electric energy by electric field 503 UvdW: semi-empirical vdW energy 504 505 (see also PRB 72, 045121(2005) for the energy contributions) 506 507 508 509 Chemical potential (Hartree) -0.234375000000 510 511*********************************************************** 512*********************************************************** 513 SCF history at MD= 7 514*********************************************************** 515*********************************************************** 516 517 SCF= 1 NormRD= 1.000000000000 Uele= -8.115458331850 518 SCF= 2 NormRD= 0.000167683722 Uele= -8.114681892488 519 SCF= 3 NormRD= 0.000045162469 Uele= -8.115204963487 520 SCF= 4 NormRD= 0.000011615855 Uele= -8.115131538540 521 SCF= 5 NormRD= 0.000012063001 Uele= -8.115185705840 522 SCF= 6 NormRD= 0.000000770921 Uele= -8.115149864665 523 SCF= 7 NormRD= 0.000000219056 Uele= -8.115151311548 524 SCF= 8 NormRD= 0.000000049780 Uele= -8.115151675197 525 SCF= 9 NormRD= 0.000000002319 Uele= -8.115151731511 526 SCF= 10 NormRD= 0.000000000867 Uele= -8.115151728344 527 528******************************************************* 529 Total energy (Hartree) at MD = 7 530******************************************************* 531 532 Uele. -8.115151728344 533 534 Ukin. 25.727236436481 535 UH0. -46.815478896272 536 UH1. 0.098979956075 537 Una. -32.236829622838 538 Unl. 6.907012717792 539 Uxc0. -4.586376950973 540 Uxc1. -4.586376950973 541 Ucore. 20.548870011531 542 Uhub. 0.000000000000 543 Ucs. 0.000000000000 544 Uzs. 0.000000000000 545 Uzo. 0.000000000000 546 Uef. 0.000000000000 547 UvdW 0.000000000000 548 Utot. -34.942963299178 549 550 Note: 551 552 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 553 554 Uene: band energy 555 Ukin: kinetic energy 556 UH0: electric part of screened Coulomb energy 557 UH1: difference electron-electron Coulomb energy 558 Una: neutral atom potential energy 559 Unl: non-local potential energy 560 Uxc0: exchange-correlation energy for alpha spin 561 Uxc1: exchange-correlation energy for beta spin 562 Ucore: core-core Coulomb energy 563 Uhub: LDA+U energy 564 Ucs: constraint energy for spin orientation 565 Uzs: Zeeman term for spin magnetic moment 566 Uzo: Zeeman term for orbital magnetic moment 567 Uef: electric energy by electric field 568 UvdW: semi-empirical vdW energy 569 570 (see also PRB 72, 045121(2005) for the energy contributions) 571 572 573 574 Chemical potential (Hartree) -0.234375000000 575 576*********************************************************** 577*********************************************************** 578 SCF history at MD= 8 579*********************************************************** 580*********************************************************** 581 582 SCF= 1 NormRD= 1.000000000000 Uele= -8.114715317995 583 SCF= 2 NormRD= 0.000196537175 Uele= -8.115631641589 584 SCF= 3 NormRD= 0.000045729380 Uele= -8.114982495267 585 SCF= 4 NormRD= 0.000009501631 Uele= -8.115078952646 586 SCF= 5 NormRD= 0.000008818511 Uele= -8.115029421207 587 SCF= 6 NormRD= 0.000000493411 Uele= -8.115057813343 588 SCF= 7 NormRD= 0.000000146268 Uele= -8.115056758377 589 SCF= 8 NormRD= 0.000000026178 Uele= -8.115056585269 590 SCF= 9 NormRD= 0.000000002024 Uele= -8.115056522182 591 SCF= 10 NormRD= 0.000000000316 Uele= -8.115056520116 592 593******************************************************* 594 Total energy (Hartree) at MD = 8 595******************************************************* 596 597 Uele. -8.115056520116 598 599 Ukin. 25.727074574812 600 UH0. -46.816359954393 601 UH1. 0.098975955798 602 Una. -32.236501942650 603 Unl. 6.906980348829 604 Uxc0. -4.586356414371 605 Uxc1. -4.586356414371 606 Ucore. 20.549578781776 607 Uhub. 0.000000000000 608 Ucs. 0.000000000000 609 Uzs. 0.000000000000 610 Uzo. 0.000000000000 611 Uef. 0.000000000000 612 UvdW 0.000000000000 613 Utot. -34.942965064570 614 615 Note: 616 617 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 618 619 Uene: band energy 620 Ukin: kinetic energy 621 UH0: electric part of screened Coulomb energy 622 UH1: difference electron-electron Coulomb energy 623 Una: neutral atom potential energy 624 Unl: non-local potential energy 625 Uxc0: exchange-correlation energy for alpha spin 626 Uxc1: exchange-correlation energy for beta spin 627 Ucore: core-core Coulomb energy 628 Uhub: LDA+U energy 629 Ucs: constraint energy for spin orientation 630 Uzs: Zeeman term for spin magnetic moment 631 Uzo: Zeeman term for orbital magnetic moment 632 Uef: electric energy by electric field 633 UvdW: semi-empirical vdW energy 634 635 (see also PRB 72, 045121(2005) for the energy contributions) 636 637 638 639 Chemical potential (Hartree) -0.234375000000 640 641*********************************************************** 642*********************************************************** 643 SCF history at MD= 9 644*********************************************************** 645*********************************************************** 646 647 SCF= 1 NormRD= 1.000000000000 Uele= -8.115747238740 648 SCF= 2 NormRD= 0.000234126088 Uele= -8.114610661941 649 SCF= 3 NormRD= 0.000057714924 Uele= -8.115392353462 650 SCF= 4 NormRD= 0.000013210118 Uele= -8.115279265209 651 SCF= 5 NormRD= 0.000012899870 Uele= -8.115347587823 652 SCF= 6 NormRD= 0.000000817714 Uele= -8.115305506138 653 SCF= 7 NormRD= 0.000000157783 Uele= -8.115307459145 654 SCF= 8 NormRD= 0.000000045975 Uele= -8.115307669555 655 SCF= 9 NormRD= 0.000000002325 Uele= -8.115307748726 656 SCF= 10 NormRD= 0.000000000490 Uele= -8.115307750431 657 658******************************************************* 659 Total energy (Hartree) at MD = 9 660******************************************************* 661 662 Uele. -8.115307750431 663 664 Ukin. 25.727807475150 665 UH0. -46.818074874485 666 UH1. 0.098995026781 667 Una. -32.237762213284 668 Unl. 6.907031910056 669 Uxc0. -4.586438611091 670 Uxc1. -4.586438611091 671 Ucore. 20.551912284788 672 Uhub. 0.000000000000 673 Ucs. 0.000000000000 674 Uzs. 0.000000000000 675 Uzo. 0.000000000000 676 Uef. 0.000000000000 677 UvdW 0.000000000000 678 Utot. -34.942967613175 679 680 Note: 681 682 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 683 684 Uene: band energy 685 Ukin: kinetic energy 686 UH0: electric part of screened Coulomb energy 687 UH1: difference electron-electron Coulomb energy 688 Una: neutral atom potential energy 689 Unl: non-local potential energy 690 Uxc0: exchange-correlation energy for alpha spin 691 Uxc1: exchange-correlation energy for beta spin 692 Ucore: core-core Coulomb energy 693 Uhub: LDA+U energy 694 Ucs: constraint energy for spin orientation 695 Uzs: Zeeman term for spin magnetic moment 696 Uzo: Zeeman term for orbital magnetic moment 697 Uef: electric energy by electric field 698 UvdW: semi-empirical vdW energy 699 700 (see also PRB 72, 045121(2005) for the energy contributions) 701 702 703 704 Chemical potential (Hartree) -0.234375000000 705 706*********************************************************** 707*********************************************************** 708 SCF history at MD=10 709*********************************************************** 710*********************************************************** 711 712 SCF= 1 NormRD= 1.000000000000 Uele= -8.113946775496 713 SCF= 2 NormRD= 0.000205245844 Uele= -8.114855977498 714 SCF= 3 NormRD= 0.000046271318 Uele= -8.114189526291 715 SCF= 4 NormRD= 0.000009460223 Uele= -8.114291460223 716 SCF= 5 NormRD= 0.000008252672 Uele= -8.114244896635 717 SCF= 6 NormRD= 0.000000482649 Uele= -8.114270901980 718 SCF= 7 NormRD= 0.000000168573 Uele= -8.114269925434 719 SCF= 8 NormRD= 0.000000044474 Uele= -8.114269706075 720 SCF= 9 NormRD= 0.000000006374 Uele= -8.114269707835 721 722******************************************************* 723 Total energy (Hartree) at MD =10 724******************************************************* 725 726 Uele. -8.114269707835 727 728 Ukin. 25.725547926734 729 UH0. -46.819079774364 730 UH1. 0.098938052887 731 Una. -32.233576468608 732 Unl. 6.906742132249 733 Uxc0. -4.586170524537 734 Uxc1. -4.586170524537 735 Ucore. 20.550795718330 736 Uhub. 0.000000000000 737 Ucs. 0.000000000000 738 Uzs. 0.000000000000 739 Uzo. 0.000000000000 740 Uef. 0.000000000000 741 UvdW 0.000000000000 742 Utot. -34.942973461846 743 744 Note: 745 746 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 747 748 Uene: band energy 749 Ukin: kinetic energy 750 UH0: electric part of screened Coulomb energy 751 UH1: difference electron-electron Coulomb energy 752 Una: neutral atom potential energy 753 Unl: non-local potential energy 754 Uxc0: exchange-correlation energy for alpha spin 755 Uxc1: exchange-correlation energy for beta spin 756 Ucore: core-core Coulomb energy 757 Uhub: LDA+U energy 758 Ucs: constraint energy for spin orientation 759 Uzs: Zeeman term for spin magnetic moment 760 Uzo: Zeeman term for orbital magnetic moment 761 Uef: electric energy by electric field 762 UvdW: semi-empirical vdW energy 763 764 (see also PRB 72, 045121(2005) for the energy contributions) 765 766 767 768 Chemical potential (Hartree) -0.234375000000 769 770*********************************************************** 771*********************************************************** 772 SCF history at MD=11 773*********************************************************** 774*********************************************************** 775 776 SCF= 1 NormRD= 1.000000000000 Uele= -8.127554023420 777 SCF= 2 NormRD= 0.003885052376 Uele= -8.107823016447 778 SCF= 3 NormRD= 0.001082966139 Uele= -8.121027870821 779 SCF= 4 NormRD= 0.000288129734 Uele= -8.119236339336 780 SCF= 5 NormRD= 0.000311333534 Uele= -8.120724651092 781 SCF= 6 NormRD= 0.000016817600 Uele= -8.119711299402 782 SCF= 7 NormRD= 0.000001613569 Uele= -8.119754595655 783 SCF= 8 NormRD= 0.000000283337 Uele= -8.119758975746 784 SCF= 9 NormRD= 0.000000130367 Uele= -8.119759076113 785 SCF= 10 NormRD= 0.000000011274 Uele= -8.119759098483 786 SCF= 11 NormRD= 0.000000001505 Uele= -8.119759065910 787 SCF= 12 NormRD= 0.000000000074 Uele= -8.119759068711 788 789******************************************************* 790 Total energy (Hartree) at MD =11 791******************************************************* 792 793 Uele. -8.119759068711 794 795 Ukin. 25.739015665921 796 UH0. -46.832946370788 797 UH1. 0.099282727532 798 Una. -32.257717042256 799 Unl. 6.908126689346 800 Uxc0. -4.587729188872 801 Uxc1. -4.587729188872 802 Ucore. 20.576725995829 803 Uhub. 0.000000000000 804 Ucs. 0.000000000000 805 Uzs. 0.000000000000 806 Uzo. 0.000000000000 807 Uef. 0.000000000000 808 UvdW 0.000000000000 809 Utot. -34.942970712160 810 811 Note: 812 813 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 814 815 Uene: band energy 816 Ukin: kinetic energy 817 UH0: electric part of screened Coulomb energy 818 UH1: difference electron-electron Coulomb energy 819 Una: neutral atom potential energy 820 Unl: non-local potential energy 821 Uxc0: exchange-correlation energy for alpha spin 822 Uxc1: exchange-correlation energy for beta spin 823 Ucore: core-core Coulomb energy 824 Uhub: LDA+U energy 825 Ucs: constraint energy for spin orientation 826 Uzs: Zeeman term for spin magnetic moment 827 Uzo: Zeeman term for orbital magnetic moment 828 Uef: electric energy by electric field 829 UvdW: semi-empirical vdW energy 830 831 (see also PRB 72, 045121(2005) for the energy contributions) 832 833 834 835 Chemical potential (Hartree) -0.234375000000 836 837*********************************************************** 838*********************************************************** 839 SCF history at MD=12 840*********************************************************** 841*********************************************************** 842 843 SCF= 1 NormRD= 1.000000000000 Uele= -8.046918189902 844 SCF= 2 NormRD= 0.022918960370 Uele= -8.156515288615 845 SCF= 3 NormRD= 0.005565080767 Uele= -8.078551072371 846 SCF= 4 NormRD= 0.001162405348 Uele= -8.090556172384 847 SCF= 5 NormRD= 0.001114763737 Uele= -8.084147829559 848 SCF= 6 NormRD= 0.000057645625 Uele= -8.087821350604 849 SCF= 7 NormRD= 0.000008917846 Uele= -8.087684048710 850 SCF= 8 NormRD= 0.000003677140 Uele= -8.087667226718 851 SCF= 9 NormRD= 0.000000796206 Uele= -8.087664577062 852 SCF= 10 NormRD= 0.000000034239 Uele= -8.087662990979 853 SCF= 11 NormRD= 0.000000004377 Uele= -8.087662901846 854 SCF= 12 NormRD= 0.000000000389 Uele= -8.087662912999 855 SCF= 13 NormRD= 0.000000000056 Uele= -8.087662912698 856 857******************************************************* 858 Total energy (Hartree) at MD =12 859******************************************************* 860 861 Uele. -8.087662912698 862 863 Ukin. 25.660248442858 864 UH0. -46.771218409102 865 UH1. 0.097287260728 866 Una. -32.116802462956 867 Unl. 6.900265029214 868 Uxc0. -4.578599342066 869 Uxc1. -4.578599342066 870 Ucore. 20.444685651619 871 Uhub. 0.000000000000 872 Ucs. 0.000000000000 873 Uzs. 0.000000000000 874 Uzo. 0.000000000000 875 Uef. 0.000000000000 876 UvdW 0.000000000000 877 Utot. -34.942733171771 878 879 Note: 880 881 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 882 883 Uene: band energy 884 Ukin: kinetic energy 885 UH0: electric part of screened Coulomb energy 886 UH1: difference electron-electron Coulomb energy 887 Una: neutral atom potential energy 888 Unl: non-local potential energy 889 Uxc0: exchange-correlation energy for alpha spin 890 Uxc1: exchange-correlation energy for beta spin 891 Ucore: core-core Coulomb energy 892 Uhub: LDA+U energy 893 Ucs: constraint energy for spin orientation 894 Uzs: Zeeman term for spin magnetic moment 895 Uzo: Zeeman term for orbital magnetic moment 896 Uef: electric energy by electric field 897 UvdW: semi-empirical vdW energy 898 899 (see also PRB 72, 045121(2005) for the energy contributions) 900 901 902 903 Chemical potential (Hartree) -0.234375000000 904 905*********************************************************** 906*********************************************************** 907 SCF history at MD=13 908*********************************************************** 909*********************************************************** 910 911 SCF= 1 NormRD= 1.000000000000 Uele= -8.110189647137 912 SCF= 2 NormRD= 0.000719191485 Uele= -8.108764422992 913 SCF= 3 NormRD= 0.000296926103 Uele= -8.108848969858 914 SCF= 4 NormRD= 0.000136163006 Uele= -8.108947289852 915 SCF= 5 NormRD= 0.000128502006 Uele= -8.108979540342 916 SCF= 6 NormRD= 0.000011513783 Uele= -8.108996177850 917 SCF= 7 NormRD= 0.000000581962 Uele= -8.108998623640 918 SCF= 8 NormRD= 0.000000306266 Uele= -8.108997511557 919 SCF= 9 NormRD= 0.000000170665 Uele= -8.108998741946 920 SCF= 10 NormRD= 0.000000023200 Uele= -8.108998312067 921 SCF= 11 NormRD= 0.000000000987 Uele= -8.108998259671 922 SCF= 12 NormRD= 0.000000000156 Uele= -8.108998258406 923 924******************************************************* 925 Total energy (Hartree) at MD =13 926******************************************************* 927 928 Uele. -8.108998258406 929 930 Ukin. 25.719461055814 931 UH0. -46.818963320200 932 UH1. 0.098807743822 933 Una. -32.219120941799 934 Unl. 6.904407780817 935 Uxc0. -4.585223313600 936 Uxc1. -4.585223313600 937 Ucore. 20.542878218685 938 Uhub. 0.000000000000 939 Ucs. 0.000000000000 940 Uzs. 0.000000000000 941 Uzo. 0.000000000000 942 Uef. 0.000000000000 943 UvdW 0.000000000000 944 Utot. -34.942976090061 945 946 Note: 947 948 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 949 950 Uene: band energy 951 Ukin: kinetic energy 952 UH0: electric part of screened Coulomb energy 953 UH1: difference electron-electron Coulomb energy 954 Una: neutral atom potential energy 955 Unl: non-local potential energy 956 Uxc0: exchange-correlation energy for alpha spin 957 Uxc1: exchange-correlation energy for beta spin 958 Ucore: core-core Coulomb energy 959 Uhub: LDA+U energy 960 Ucs: constraint energy for spin orientation 961 Uzs: Zeeman term for spin magnetic moment 962 Uzo: Zeeman term for orbital magnetic moment 963 Uef: electric energy by electric field 964 UvdW: semi-empirical vdW energy 965 966 (see also PRB 72, 045121(2005) for the energy contributions) 967 968 969 970 Chemical potential (Hartree) -0.234375000000 971 972*********************************************************** 973*********************************************************** 974 SCF history at MD=14 975*********************************************************** 976*********************************************************** 977 978 SCF= 1 NormRD= 1.000000000000 Uele= -8.118145509278 979 SCF= 2 NormRD= 0.001810425788 Uele= -8.110278416418 980 SCF= 3 NormRD= 0.000623785061 Uele= -8.115597929040 981 SCF= 4 NormRD= 0.000197261959 Uele= -8.114940295178 982 SCF= 5 NormRD= 0.000223957064 Uele= -8.115806617104 983 SCF= 6 NormRD= 0.000010086365 Uele= -8.115158630157 984 SCF= 7 NormRD= 0.000001692524 Uele= -8.115181865425 985 SCF= 8 NormRD= 0.000001024415 Uele= -8.115184313170 986 SCF= 9 NormRD= 0.000000096236 Uele= -8.115183778495 987 SCF= 10 NormRD= 0.000000018516 Uele= -8.115183759530 988 SCF= 11 NormRD= 0.000000002350 Uele= -8.115183776881 989 SCF= 12 NormRD= 0.000000000459 Uele= -8.115183783199 990 991******************************************************* 992 Total energy (Hartree) at MD =14 993******************************************************* 994 995 Uele. -8.115183783199 996 997 Ukin. 25.729378201063 998 UH0. -46.835130343310 999 UH1. 0.099040359023 1000 Una. -32.239669549042 1001 Unl. 6.906789622080 1002 Uxc0. -4.586571960060 1003 Uxc1. -4.586571960060 1004 Ucore. 20.569735420164 1005 Uhub. 0.000000000000 1006 Ucs. 0.000000000000 1007 Uzs. 0.000000000000 1008 Uzo. 0.000000000000 1009 Uef. 0.000000000000 1010 UvdW 0.000000000000 1011 Utot. -34.943000210142 1012 1013 Note: 1014 1015 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 1016 1017 Uene: band energy 1018 Ukin: kinetic energy 1019 UH0: electric part of screened Coulomb energy 1020 UH1: difference electron-electron Coulomb energy 1021 Una: neutral atom potential energy 1022 Unl: non-local potential energy 1023 Uxc0: exchange-correlation energy for alpha spin 1024 Uxc1: exchange-correlation energy for beta spin 1025 Ucore: core-core Coulomb energy 1026 Uhub: LDA+U energy 1027 Ucs: constraint energy for spin orientation 1028 Uzs: Zeeman term for spin magnetic moment 1029 Uzo: Zeeman term for orbital magnetic moment 1030 Uef: electric energy by electric field 1031 UvdW: semi-empirical vdW energy 1032 1033 (see also PRB 72, 045121(2005) for the energy contributions) 1034 1035 1036 1037 Chemical potential (Hartree) -0.234375000000 1038 1039*********************************************************** 1040*********************************************************** 1041 SCF history at MD=15 1042*********************************************************** 1043*********************************************************** 1044 1045 SCF= 1 NormRD= 1.000000000000 Uele= -8.112447359911 1046 SCF= 2 NormRD= 0.002994437770 Uele= -8.125044343051 1047 SCF= 3 NormRD= 0.000592081823 Uele= -8.115677471669 1048 SCF= 4 NormRD= 0.000105531633 Uele= -8.117153245342 1049 SCF= 5 NormRD= 0.000062664803 Uele= -8.116687464139 1050 SCF= 6 NormRD= 0.000005683815 Uele= -8.116881365239 1051 SCF= 7 NormRD= 0.000002907613 Uele= -8.116873288608 1052 SCF= 8 NormRD= 0.000000480118 Uele= -8.116869372819 1053 SCF= 9 NormRD= 0.000000083172 Uele= -8.116869337782 1054 SCF= 10 NormRD= 0.000000009134 Uele= -8.116869214701 1055 SCF= 11 NormRD= 0.000000001921 Uele= -8.116869188821 1056 SCF= 12 NormRD= 0.000000000054 Uele= -8.116869192876 1057 1058******************************************************* 1059 Total energy (Hartree) at MD =15 1060******************************************************* 1061 1062 Uele. -8.116869192876 1063 1064 Ukin. 25.730853304799 1065 UH0. -46.843143724251 1066 UH1. 0.099067387034 1067 Una. -32.243625602064 1068 Unl. 6.907596682923 1069 Uxc0. -4.586839881826 1070 Uxc1. -4.586839881826 1071 Ucore. 20.579920572814 1072 Uhub. 0.000000000000 1073 Ucs. 0.000000000000 1074 Uzs. 0.000000000000 1075 Uzo. 0.000000000000 1076 Uef. 0.000000000000 1077 UvdW 0.000000000000 1078 Utot. -34.943011142397 1079 1080 Note: 1081 1082 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 1083 1084 Uene: band energy 1085 Ukin: kinetic energy 1086 UH0: electric part of screened Coulomb energy 1087 UH1: difference electron-electron Coulomb energy 1088 Una: neutral atom potential energy 1089 Unl: non-local potential energy 1090 Uxc0: exchange-correlation energy for alpha spin 1091 Uxc1: exchange-correlation energy for beta spin 1092 Ucore: core-core Coulomb energy 1093 Uhub: LDA+U energy 1094 Ucs: constraint energy for spin orientation 1095 Uzs: Zeeman term for spin magnetic moment 1096 Uzo: Zeeman term for orbital magnetic moment 1097 Uef: electric energy by electric field 1098 UvdW: semi-empirical vdW energy 1099 1100 (see also PRB 72, 045121(2005) for the energy contributions) 1101 1102 1103 1104 Chemical potential (Hartree) -0.234375000000 1105 1106*********************************************************** 1107*********************************************************** 1108 SCF history at MD=16 1109*********************************************************** 1110*********************************************************** 1111 1112 SCF= 1 NormRD= 1.000000000000 Uele= -8.141912247517 1113 SCF= 2 NormRD= 0.013150321285 Uele= -8.113876734282 1114 SCF= 3 NormRD= 0.005274225846 Uele= -8.122688132789 1115 SCF= 4 NormRD= 0.002182162431 Uele= -8.123976458009 1116 SCF= 5 NormRD= 0.000637163604 Uele= -8.126536316334 1117 SCF= 6 NormRD= 0.000106500337 Uele= -8.125278571264 1118 SCF= 7 NormRD= 0.000005550247 Uele= -8.125436515613 1119 SCF= 8 NormRD= 0.000005503309 Uele= -8.125457793535 1120 SCF= 9 NormRD= 0.000000541876 Uele= -8.125445269332 1121 SCF= 10 NormRD= 0.000000155829 Uele= -8.125444543896 1122 SCF= 11 NormRD= 0.000000010853 Uele= -8.125444286109 1123 SCF= 12 NormRD= 0.000000002371 Uele= -8.125444271632 1124 SCF= 13 NormRD= 0.000000000616 Uele= -8.125444273844 1125 1126******************************************************* 1127 Total energy (Hartree) at MD =16 1128******************************************************* 1129 1130 Uele. -8.125444273844 1131 1132 Ukin. 25.740096662487 1133 UH0. -46.908179265579 1134 UH1. 0.099249360882 1135 Una. -32.266189099854 1136 Unl. 6.911529861152 1137 Uxc0. -4.588354078766 1138 Uxc1. -4.588354078766 1139 Ucore. 20.657168819462 1140 Uhub. 0.000000000000 1141 Ucs. 0.000000000000 1142 Uzs. 0.000000000000 1143 Uzo. 0.000000000000 1144 Uef. 0.000000000000 1145 UvdW 0.000000000000 1146 Utot. -34.943031818983 1147 1148 Note: 1149 1150 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 1151 1152 Uene: band energy 1153 Ukin: kinetic energy 1154 UH0: electric part of screened Coulomb energy 1155 UH1: difference electron-electron Coulomb energy 1156 Una: neutral atom potential energy 1157 Unl: non-local potential energy 1158 Uxc0: exchange-correlation energy for alpha spin 1159 Uxc1: exchange-correlation energy for beta spin 1160 Ucore: core-core Coulomb energy 1161 Uhub: LDA+U energy 1162 Ucs: constraint energy for spin orientation 1163 Uzs: Zeeman term for spin magnetic moment 1164 Uzo: Zeeman term for orbital magnetic moment 1165 Uef: electric energy by electric field 1166 UvdW: semi-empirical vdW energy 1167 1168 (see also PRB 72, 045121(2005) for the energy contributions) 1169 1170 1171 1172 Chemical potential (Hartree) -0.234375000000 1173 1174*********************************************************** 1175*********************************************************** 1176 SCF history at MD=17 1177*********************************************************** 1178*********************************************************** 1179 1180 SCF= 1 NormRD= 1.000000000000 Uele= -8.116809096014 1181 SCF= 2 NormRD= 0.001162161803 Uele= -8.121904301816 1182 SCF= 3 NormRD= 0.000315083391 Uele= -8.118518108362 1183 SCF= 4 NormRD= 0.000111737517 Uele= -8.118969968643 1184 SCF= 5 NormRD= 0.000091953861 Uele= -8.118581760855 1185 SCF= 6 NormRD= 0.000022141434 Uele= -8.118900113855 1186 SCF= 7 NormRD= 0.000001396364 Uele= -8.118841609345 1187 SCF= 8 NormRD= 0.000000501122 Uele= -8.118840419474 1188 SCF= 9 NormRD= 0.000000022510 Uele= -8.118840857715 1189 SCF= 10 NormRD= 0.000000004784 Uele= -8.118840862209 1190 1191******************************************************* 1192 Total energy (Hartree) at MD =17 1193******************************************************* 1194 1195 Uele. -8.118840862209 1196 1197 Ukin. 25.730974160539 1198 UH0. -46.879833409571 1199 UH1. 0.099045244830 1200 Una. -32.246149125266 1201 Unl. 6.908782470220 1202 Uxc0. -4.587040661852 1203 Uxc1. -4.587040661852 1204 Ucore. 20.618198851161 1205 Uhub. 0.000000000000 1206 Ucs. 0.000000000000 1207 Uzs. 0.000000000000 1208 Uzo. 0.000000000000 1209 Uef. 0.000000000000 1210 UvdW 0.000000000000 1211 Utot. -34.943063131792 1212 1213 Note: 1214 1215 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 1216 1217 Uene: band energy 1218 Ukin: kinetic energy 1219 UH0: electric part of screened Coulomb energy 1220 UH1: difference electron-electron Coulomb energy 1221 Una: neutral atom potential energy 1222 Unl: non-local potential energy 1223 Uxc0: exchange-correlation energy for alpha spin 1224 Uxc1: exchange-correlation energy for beta spin 1225 Ucore: core-core Coulomb energy 1226 Uhub: LDA+U energy 1227 Ucs: constraint energy for spin orientation 1228 Uzs: Zeeman term for spin magnetic moment 1229 Uzo: Zeeman term for orbital magnetic moment 1230 Uef: electric energy by electric field 1231 UvdW: semi-empirical vdW energy 1232 1233 (see also PRB 72, 045121(2005) for the energy contributions) 1234 1235 1236 1237 Chemical potential (Hartree) -0.234375000000 1238 1239*********************************************************** 1240*********************************************************** 1241 SCF history at MD=18 1242*********************************************************** 1243*********************************************************** 1244 1245 SCF= 1 NormRD= 1.000000000000 Uele= -8.117023279211 1246 SCF= 2 NormRD= 0.000118907891 Uele= -8.117512749477 1247 SCF= 3 NormRD= 0.000030380704 Uele= -8.117175934843 1248 SCF= 4 NormRD= 0.000005754845 Uele= -8.117225141555 1249 SCF= 5 NormRD= 0.000007168185 Uele= -8.117194750896 1250 SCF= 6 NormRD= 0.000000393975 Uele= -8.117211765600 1251 SCF= 7 NormRD= 0.000000191764 Uele= -8.117212603381 1252 SCF= 8 NormRD= 0.000000038194 Uele= -8.117212312274 1253 SCF= 9 NormRD= 0.000000001598 Uele= -8.117212406170 1254 SCF= 10 NormRD= 0.000000000320 Uele= -8.117212409220 1255 1256******************************************************* 1257 Total energy (Hartree) at MD =18 1258******************************************************* 1259 1260 Uele. -8.117212409220 1261 1262 Ukin. 25.728604831603 1263 UH0. -46.872828054373 1264 UH1. 0.098991660812 1265 Una. -32.241055328396 1266 Unl. 6.908122080808 1267 Uxc0. -4.586705754165 1268 Uxc1. -4.586705754165 1269 Ucore. 20.608513023332 1270 Uhub. 0.000000000000 1271 Ucs. 0.000000000000 1272 Uzs. 0.000000000000 1273 Uzo. 0.000000000000 1274 Uef. 0.000000000000 1275 UvdW 0.000000000000 1276 Utot. -34.943063294544 1277 1278 Note: 1279 1280 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 1281 1282 Uene: band energy 1283 Ukin: kinetic energy 1284 UH0: electric part of screened Coulomb energy 1285 UH1: difference electron-electron Coulomb energy 1286 Una: neutral atom potential energy 1287 Unl: non-local potential energy 1288 Uxc0: exchange-correlation energy for alpha spin 1289 Uxc1: exchange-correlation energy for beta spin 1290 Ucore: core-core Coulomb energy 1291 Uhub: LDA+U energy 1292 Ucs: constraint energy for spin orientation 1293 Uzs: Zeeman term for spin magnetic moment 1294 Uzo: Zeeman term for orbital magnetic moment 1295 Uef: electric energy by electric field 1296 UvdW: semi-empirical vdW energy 1297 1298 (see also PRB 72, 045121(2005) for the energy contributions) 1299 1300 1301 1302 Chemical potential (Hartree) -0.234375000000 1303 1304*********************************************************** 1305*********************************************************** 1306 SCF history at MD=19 1307*********************************************************** 1308*********************************************************** 1309 1310 SCF= 1 NormRD= 1.000000000000 Uele= -8.106759293028 1311 SCF= 2 NormRD= 0.005151990124 Uele= -8.118175877751 1312 SCF= 3 NormRD= 0.002060012168 Uele= -8.114300037549 1313 SCF= 4 NormRD= 0.000846562085 Uele= -8.113881291893 1314 SCF= 5 NormRD= 0.000299429611 Uele= -8.112761828254 1315 SCF= 6 NormRD= 0.000034318627 Uele= -8.113363477661 1316 SCF= 7 NormRD= 0.000002372112 Uele= -8.113312496562 1317 SCF= 8 NormRD= 0.000002542209 Uele= -8.113302037980 1318 SCF= 9 NormRD= 0.000000238110 Uele= -8.113307598048 1319 SCF= 10 NormRD= 0.000000058604 Uele= -8.113307797078 1320 SCF= 11 NormRD= 0.000000006028 Uele= -8.113307916781 1321 SCF= 12 NormRD= 0.000000001488 Uele= -8.113307924312 1322 1323******************************************************* 1324 Total energy (Hartree) at MD =19 1325******************************************************* 1326 1327 Uele. -8.113307924312 1328 1329 Ukin. 25.723535105883 1330 UH0. -46.846783728335 1331 UH1. 0.098883300579 1332 Una. -32.229632780223 1333 Unl. 6.906438411996 1334 Uxc0. -4.585941245450 1335 Uxc1. -4.585941245450 1336 Ucore. 20.576408798953 1337 Uhub. 0.000000000000 1338 Ucs. 0.000000000000 1339 Uzs. 0.000000000000 1340 Uzo. 0.000000000000 1341 Uef. 0.000000000000 1342 UvdW 0.000000000000 1343 Utot. -34.943033382049 1344 1345 Note: 1346 1347 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 1348 1349 Uene: band energy 1350 Ukin: kinetic energy 1351 UH0: electric part of screened Coulomb energy 1352 UH1: difference electron-electron Coulomb energy 1353 Una: neutral atom potential energy 1354 Unl: non-local potential energy 1355 Uxc0: exchange-correlation energy for alpha spin 1356 Uxc1: exchange-correlation energy for beta spin 1357 Ucore: core-core Coulomb energy 1358 Uhub: LDA+U energy 1359 Ucs: constraint energy for spin orientation 1360 Uzs: Zeeman term for spin magnetic moment 1361 Uzo: Zeeman term for orbital magnetic moment 1362 Uef: electric energy by electric field 1363 UvdW: semi-empirical vdW energy 1364 1365 (see also PRB 72, 045121(2005) for the energy contributions) 1366 1367 1368 1369 Chemical potential (Hartree) -0.234375000000 1370 1371*********************************************************** 1372*********************************************************** 1373 SCF history at MD=20 1374*********************************************************** 1375*********************************************************** 1376 1377 SCF= 1 NormRD= 1.000000000000 Uele= -8.119037768082 1378 SCF= 2 NormRD= 0.000765675934 Uele= -8.115714547314 1379 SCF= 3 NormRD= 0.000206029994 Uele= -8.117985063317 1380 SCF= 4 NormRD= 0.000079419216 Uele= -8.117668875576 1381 SCF= 5 NormRD= 0.000065625816 Uele= -8.117938003354 1382 SCF= 6 NormRD= 0.000015029346 Uele= -8.117702243363 1383 SCF= 7 NormRD= 0.000000537369 Uele= -8.117745781746 1384 SCF= 8 NormRD= 0.000000116000 Uele= -8.117746571035 1385 SCF= 9 NormRD= 0.000000019085 Uele= -8.117746463893 1386 SCF= 10 NormRD= 0.000000007929 Uele= -8.117746473795 1387 1388******************************************************* 1389 Total energy (Hartree) at MD =20 1390******************************************************* 1391 1392 Uele. -8.117746473795 1393 1394 Ukin. 25.729685659624 1395 UH0. -46.891506003048 1396 UH1. 0.099012947773 1397 Una. -32.243139491872 1398 Unl. 6.908306399029 1399 Uxc0. -4.586842540142 1400 Uxc1. -4.586842540142 1401 Ucore. 20.628251976487 1402 Uhub. 0.000000000000 1403 Ucs. 0.000000000000 1404 Uzs. 0.000000000000 1405 Uzo. 0.000000000000 1406 Uef. 0.000000000000 1407 UvdW 0.000000000000 1408 Utot. -34.943073592290 1409 1410 Note: 1411 1412 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 1413 1414 Uene: band energy 1415 Ukin: kinetic energy 1416 UH0: electric part of screened Coulomb energy 1417 UH1: difference electron-electron Coulomb energy 1418 Una: neutral atom potential energy 1419 Unl: non-local potential energy 1420 Uxc0: exchange-correlation energy for alpha spin 1421 Uxc1: exchange-correlation energy for beta spin 1422 Ucore: core-core Coulomb energy 1423 Uhub: LDA+U energy 1424 Ucs: constraint energy for spin orientation 1425 Uzs: Zeeman term for spin magnetic moment 1426 Uzo: Zeeman term for orbital magnetic moment 1427 Uef: electric energy by electric field 1428 UvdW: semi-empirical vdW energy 1429 1430 (see also PRB 72, 045121(2005) for the energy contributions) 1431 1432 1433 1434 Chemical potential (Hartree) -0.234375000000 1435 1436*********************************************************** 1437*********************************************************** 1438 SCF history at MD=21 1439*********************************************************** 1440*********************************************************** 1441 1442 SCF= 1 NormRD= 1.000000000000 Uele= -8.114318487174 1443 SCF= 2 NormRD= 0.000359027378 Uele= -8.116168065610 1444 SCF= 3 NormRD= 0.000112719130 Uele= -8.114977779291 1445 SCF= 4 NormRD= 0.000032603931 Uele= -8.115134501084 1446 SCF= 5 NormRD= 0.000036293189 Uele= -8.114974486248 1447 SCF= 6 NormRD= 0.000002214356 Uele= -8.115089303492 1448 SCF= 7 NormRD= 0.000000417276 Uele= -8.115084318938 1449 SCF= 8 NormRD= 0.000000187588 Uele= -8.115083619647 1450 SCF= 9 NormRD= 0.000000012240 Uele= -8.115083351776 1451 SCF= 10 NormRD= 0.000000002045 Uele= -8.115083345173 1452 1453******************************************************* 1454 Total energy (Hartree) at MD =21 1455******************************************************* 1456 1457 Uele. -8.115083345173 1458 1459 Ukin. 25.726270919976 1460 UH0. -46.905255701377 1461 UH1. 0.098930424459 1462 Una. -32.235492164789 1463 Unl. 6.907194231598 1464 Uxc0. -4.586333134502 1465 Uxc1. -4.586333134502 1466 Ucore. 20.637943009127 1467 Uhub. 0.000000000000 1468 Ucs. 0.000000000000 1469 Uzs. 0.000000000000 1470 Uzo. 0.000000000000 1471 Uef. 0.000000000000 1472 UvdW 0.000000000000 1473 Utot. -34.943075550010 1474 1475 Note: 1476 1477 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 1478 1479 Uene: band energy 1480 Ukin: kinetic energy 1481 UH0: electric part of screened Coulomb energy 1482 UH1: difference electron-electron Coulomb energy 1483 Una: neutral atom potential energy 1484 Unl: non-local potential energy 1485 Uxc0: exchange-correlation energy for alpha spin 1486 Uxc1: exchange-correlation energy for beta spin 1487 Ucore: core-core Coulomb energy 1488 Uhub: LDA+U energy 1489 Ucs: constraint energy for spin orientation 1490 Uzs: Zeeman term for spin magnetic moment 1491 Uzo: Zeeman term for orbital magnetic moment 1492 Uef: electric energy by electric field 1493 UvdW: semi-empirical vdW energy 1494 1495 (see also PRB 72, 045121(2005) for the energy contributions) 1496 1497 1498 1499 Chemical potential (Hartree) -0.234375000000 1500 1501*********************************************************** 1502*********************************************************** 1503 SCF history at MD=22 1504*********************************************************** 1505*********************************************************** 1506 1507 SCF= 1 NormRD= 1.000000000000 Uele= -8.115065574908 1508 SCF= 2 NormRD= 0.000276413384 Uele= -8.114016966829 1509 SCF= 3 NormRD= 0.000083307533 Uele= -8.114791305961 1510 SCF= 4 NormRD= 0.000022046312 Uele= -8.114664121580 1511 SCF= 5 NormRD= 0.000031935910 Uele= -8.114760989289 1512 SCF= 6 NormRD= 0.000003516175 Uele= -8.114700694267 1513 SCF= 7 NormRD= 0.000000620901 Uele= -8.114690510230 1514 SCF= 8 NormRD= 0.000000301965 Uele= -8.114691672227 1515 SCF= 9 NormRD= 0.000000012026 Uele= -8.114691265394 1516 SCF= 10 NormRD= 0.000000001848 Uele= -8.114691279276 1517 SCF= 11 NormRD= 0.000000000132 Uele= -8.114691281415 1518 1519******************************************************* 1520 Total energy (Hartree) at MD =22 1521******************************************************* 1522 1523 Uele. -8.114691281415 1524 1525 Ukin. 25.725744857937 1526 UH0. -46.891976512147 1527 UH1. 0.098923234101 1528 Una. -32.234276622527 1529 Unl. 6.907016588230 1530 Uxc0. -4.586258362794 1531 Uxc1. -4.586258362794 1532 Ucore. 20.624006641173 1533 Uhub. 0.000000000000 1534 Ucs. 0.000000000000 1535 Uzs. 0.000000000000 1536 Uzo. 0.000000000000 1537 Uef. 0.000000000000 1538 UvdW 0.000000000000 1539 Utot. -34.943078538824 1540 1541 Note: 1542 1543 Utot = Ukin+UH0+UH1+Una+Unl+Uxc0+Uxc1+Ucore+Uhub+Ucs+Uzs+Uzo+Uef+UvdW 1544 1545 Uene: band energy 1546 Ukin: kinetic energy 1547 UH0: electric part of screened Coulomb energy 1548 UH1: difference electron-electron Coulomb energy 1549 Una: neutral atom potential energy 1550 Unl: non-local potential energy 1551 Uxc0: exchange-correlation energy for alpha spin 1552 Uxc1: exchange-correlation energy for beta spin 1553 Ucore: core-core Coulomb energy 1554 Uhub: LDA+U energy 1555 Ucs: constraint energy for spin orientation 1556 Uzs: Zeeman term for spin magnetic moment 1557 Uzo: Zeeman term for orbital magnetic moment 1558 Uef: electric energy by electric field 1559 UvdW: semi-empirical vdW energy 1560 1561 (see also PRB 72, 045121(2005) for the energy contributions) 1562 1563 1564 1565 Chemical potential (Hartree) -0.234375000000 1566 1567*********************************************************** 1568*********************************************************** 1569 Eigenvalues (Hartree) for SCF KS-eq. 1570*********************************************************** 1571*********************************************************** 1572 1573 Chemical Potential (Hartree) = -0.23437500000000 1574 Number of States = 16.00000000000000 1575 HOMO = 8 1576 Eigenvalues 1577 Up-spin Down-spin 1578 1 -0.94049575245929 -0.94049575245929 1579 2 -0.92592341654854 -0.92592341654854 1580 3 -0.49219583877955 -0.49219583877955 1581 4 -0.47674372309246 -0.47674372309246 1582 5 -0.35238968415513 -0.35238968415513 1583 6 -0.33785665941892 -0.33785665941892 1584 7 -0.27310882989899 -0.27310882989899 1585 8 -0.25863173611234 -0.25863173611234 1586 9 -0.00776392398041 -0.00776392398041 1587 10 0.01154383028920 0.01154383028920 1588 11 0.07925812255227 0.07925812255227 1589 12 0.09319734234626 0.09319734234626 1590 13 0.20591282907291 0.20591282907291 1591 14 0.22290845527910 0.22290845527910 1592 15 0.25303170315442 0.25303170315442 1593 16 0.26561056272344 0.26561056272344 1594 17 0.30271974747932 0.30271974747932 1595 18 0.30352509047299 0.30352509047299 1596 19 0.31262444741778 0.31262444741778 1597 20 0.31777959263499 0.31777959263499 1598 21 0.32501834199602 0.32501834199602 1599 22 0.35431880676916 0.35431880676916 1600 23 0.45121075248759 0.45121075248759 1601 24 0.46358832839348 0.46358832839348 1602 25 0.57524356207448 0.57524356207448 1603 26 0.59687456034052 0.59687456034052 1604 27 0.60465770243797 0.60465770243797 1605 28 0.61070271312772 0.61070271312772 1606 29 0.69467738535524 0.69467738535524 1607 30 0.71369579182621 0.71369579182621 1608 31 0.79547695257780 0.79547695257780 1609 32 0.81232137677079 0.81232137677079 1610 33 1.23259105988323 1.23259105988323 1611 34 1.23802969925522 1.23802969925522 1612 35 1.64695715359294 1.64695715359294 1613 36 1.65519565835887 1.65519565835887 1614 37 1.66580490543280 1.66580490543280 1615 38 1.66992769214018 1.66992769214018 1616 39 1.68267693323421 1.68267693323421 1617 40 1.70274506469291 1.70274506469291 1618 41 1.87949559101643 1.87949559101643 1619 42 1.89324359702004 1.89324359702004 1620 43 1.89476184069961 1.89476184069961 1621 44 1.91019156059415 1.91019156059415 1622 45 2.03349376771851 2.03349376771851 1623 46 2.06456268792763 2.06456268792763 1624 1625*********************************************************** 1626*********************************************************** 1627 History of geometry optimization 1628*********************************************************** 1629*********************************************************** 1630 1631 MD_iter SD_scaling |Maximum force| Maximum step Utot 1632 (Hartree/Bohr) (Ang) (Hartree) 1633 1634 1 1.25981732 0.01723476 0.01148984 -34.94228246 1635 2 1.25981732 0.00285947 0.00190632 -34.94294256 1636 3 1.25981732 0.00058985 0.00039323 -34.94295839 1637 4 1.25981732 0.00043920 0.00029280 -34.94295943 1638 5 3.14954330 0.00043888 0.00073146 -34.94296010 1639 6 3.14954330 0.00040720 0.00067866 -34.94296169 1640 7 3.14954330 0.00043157 0.00071929 -34.94296330 1641 8 3.14954330 0.00053198 0.00088664 -34.94296506 1642 9 7.87385824 0.00050429 0.00210120 -34.94296761 1643 10 7.87385824 0.00076618 0.00319241 -34.94297346 1644 11 7.87385824 0.00176343 0.00734761 -34.94297071 1645 12 7.87385824 0.01069847 0.00975511 -34.94273317 1646 13 7.87385824 0.00157368 0.00336810 -34.94297609 1647 14 7.87385824 0.00075042 0.00465418 -34.94300021 1648 15 7.87385824 0.00065087 0.03901159 -34.94301114 1649 16 7.87385824 0.00273668 0.01291119 -34.94303182 1650 17 7.87385824 0.00103272 0.00311756 -34.94306313 1651 18 7.87385824 0.00071136 0.01469334 -34.94306329 1652 19 7.87385824 0.00143574 0.02744591 -34.94303338 1653 20 7.87385824 0.00077662 0.01322568 -34.94307359 1654 21 7.87385824 0.00043657 0.00913533 -34.94307555 1655 22 7.87385824 0.00003266 0.00000000 -34.94307854 1656 1657*********************************************************** 1658*********************************************************** 1659 Mulliken populations 1660*********************************************************** 1661*********************************************************** 1662 1663 Total spin moment (muB) 0.000000000 1664 1665 Up spin Down spin Sum Diff 1666 1 O 3.178172503 3.178172503 6.356345005 0.000000000 1667 2 H 0.411004997 0.411004997 0.822009994 0.000000000 1668 3 H 0.411003982 0.411003982 0.822007964 0.000000000 1669 4 O 3.178602829 3.178602829 6.357205659 0.000000000 1670 5 H 0.410608097 0.410608097 0.821216195 0.000000000 1671 6 H 0.410607592 0.410607592 0.821215183 0.000000000 1672 1673 Sum of MulP: up = 8.00000 down = 8.00000 1674 total= 16.00000 ideal(neutral)= 16.00000 1675 1676 1677 Decomposed Mulliken populations 1678 1679 1 O Up spin Down spin Sum Diff 1680 multiple 1681 s 0 0.883598019 0.883598019 1.767196039 0.000000000 1682 sum over m 0.883598019 0.883598019 1.767196039 0.000000000 1683 s 1 -0.003133311 -0.003133311 -0.006266623 0.000000000 1684 sum over m -0.003133311 -0.003133311 -0.006266623 0.000000000 1685 sum over m+mul 0.880464708 0.880464708 1.760929416 0.000000000 1686 px 0 0.642890974 0.642890974 1.285781948 0.000000000 1687 py 0 0.773763422 0.773763422 1.547526844 0.000000000 1688 pz 0 0.896747057 0.896747057 1.793494114 0.000000000 1689 sum over m 2.313401453 2.313401453 4.626802906 0.000000000 1690 px 1 -0.012299168 -0.012299168 -0.024598337 0.000000000 1691 py 1 -0.004636083 -0.004636083 -0.009272167 0.000000000 1692 pz 1 -0.003110542 -0.003110542 -0.006221084 0.000000000 1693 sum over m -0.020045794 -0.020045794 -0.040091587 0.000000000 1694 sum over m+mul 2.293355659 2.293355659 4.586711319 0.000000000 1695 d3z^2-r^2 0 0.001047153 0.001047153 0.002094305 0.000000000 1696 dx^2-y^2 0 0.000072259 0.000072259 0.000144519 0.000000000 1697 dxy 0 0.003096384 0.003096384 0.006192768 0.000000000 1698 dxz 0 0.000000000 0.000000000 0.000000000 0.000000000 1699 dyz 0 0.000136339 0.000136339 0.000272679 0.000000000 1700 sum over m 0.004352135 0.004352135 0.008704271 0.000000000 1701 sum over m+mul 0.004352135 0.004352135 0.008704271 0.000000000 1702 1703 2 H Up spin Down spin Sum Diff 1704 multiple 1705 s 0 0.283293111 0.283293111 0.566586222 0.000000000 1706 sum over m 0.283293111 0.283293111 0.566586222 0.000000000 1707 s 1 0.028593787 0.028593787 0.057187574 0.000000000 1708 sum over m 0.028593787 0.028593787 0.057187574 0.000000000 1709 sum over m+mul 0.311886898 0.311886898 0.623773796 0.000000000 1710 px 0 0.013196312 0.013196312 0.026392625 0.000000000 1711 py 0 0.032810157 0.032810157 0.065620315 0.000000000 1712 pz 0 0.053111629 0.053111629 0.106223258 0.000000000 1713 sum over m 0.099118099 0.099118099 0.198236198 0.000000000 1714 sum over m+mul 0.099118099 0.099118099 0.198236198 0.000000000 1715 1716 3 H Up spin Down spin Sum Diff 1717 multiple 1718 s 0 0.283290971 0.283290971 0.566581941 0.000000000 1719 sum over m 0.283290971 0.283290971 0.566581941 0.000000000 1720 s 1 0.028594260 0.028594260 0.057188519 0.000000000 1721 sum over m 0.028594260 0.028594260 0.057188519 0.000000000 1722 sum over m+mul 0.311885230 0.311885230 0.623770460 0.000000000 1723 px 0 0.013195740 0.013195740 0.026391480 0.000000000 1724 py 0 0.032810955 0.032810955 0.065621911 0.000000000 1725 pz 0 0.053112057 0.053112057 0.106224113 0.000000000 1726 sum over m 0.099118752 0.099118752 0.198237504 0.000000000 1727 sum over m+mul 0.099118752 0.099118752 0.198237504 0.000000000 1728 1729 4 O Up spin Down spin Sum Diff 1730 multiple 1731 s 0 0.882960451 0.882960451 1.765920902 0.000000000 1732 sum over m 0.882960451 0.882960451 1.765920902 0.000000000 1733 s 1 -0.003176696 -0.003176696 -0.006353392 0.000000000 1734 sum over m -0.003176696 -0.003176696 -0.006353392 0.000000000 1735 sum over m+mul 0.879783755 0.879783755 1.759567511 0.000000000 1736 px 0 0.896926428 0.896926428 1.793852856 0.000000000 1737 py 0 0.774160258 0.774160258 1.548320515 0.000000000 1738 pz 0 0.643273128 0.643273128 1.286546257 0.000000000 1739 sum over m 2.314359814 2.314359814 4.628719628 0.000000000 1740 px 1 -0.003127176 -0.003127176 -0.006254351 0.000000000 1741 py 1 -0.004571048 -0.004571048 -0.009142097 0.000000000 1742 pz 1 -0.012195461 -0.012195461 -0.024390923 0.000000000 1743 sum over m -0.019893686 -0.019893686 -0.039787371 0.000000000 1744 sum over m+mul 2.294466128 2.294466128 4.588932257 0.000000000 1745 d3z^2-r^2 0 0.000230277 0.000230277 0.000460554 0.000000000 1746 dx^2-y^2 0 0.000887430 0.000887430 0.001774860 0.000000000 1747 dxy 0 0.000141729 0.000141729 0.000283457 0.000000000 1748 dxz 0 0.000000000 0.000000000 0.000000000 0.000000000 1749 dyz 0 0.003093510 0.003093510 0.006187021 0.000000000 1750 sum over m 0.004352946 0.004352946 0.008705891 0.000000000 1751 sum over m+mul 0.004352946 0.004352946 0.008705891 0.000000000 1752 1753 5 H Up spin Down spin Sum Diff 1754 multiple 1755 s 0 0.283232214 0.283232214 0.566464428 0.000000000 1756 sum over m 0.283232214 0.283232214 0.566464428 0.000000000 1757 s 1 0.028624876 0.028624876 0.057249753 0.000000000 1758 sum over m 0.028624876 0.028624876 0.057249753 0.000000000 1759 sum over m+mul 0.311857090 0.311857090 0.623714180 0.000000000 1760 px 0 0.053016881 0.053016881 0.106033763 0.000000000 1761 py 0 0.032690744 0.032690744 0.065381487 0.000000000 1762 pz 0 0.013043382 0.013043382 0.026086765 0.000000000 1763 sum over m 0.098751007 0.098751007 0.197502014 0.000000000 1764 sum over m+mul 0.098751007 0.098751007 0.197502014 0.000000000 1765 1766 6 H Up spin Down spin Sum Diff 1767 multiple 1768 s 0 0.283231334 0.283231334 0.566462668 0.000000000 1769 sum over m 0.283231334 0.283231334 0.566462668 0.000000000 1770 s 1 0.028625033 0.028625033 0.057250066 0.000000000 1771 sum over m 0.028625033 0.028625033 0.057250066 0.000000000 1772 sum over m+mul 0.311856367 0.311856367 0.623712734 0.000000000 1773 px 0 0.053017042 0.053017042 0.106034083 0.000000000 1774 py 0 0.032691054 0.032691054 0.065382108 0.000000000 1775 pz 0 0.013043129 0.013043129 0.026086258 0.000000000 1776 sum over m 0.098751225 0.098751225 0.197502449 0.000000000 1777 sum over m+mul 0.098751225 0.098751225 0.197502449 0.000000000 1778 1779*********************************************************** 1780*********************************************************** 1781 Dipole moment (Debye) 1782*********************************************************** 1783*********************************************************** 1784 1785 Absolute D 3.74401881 1786 1787 Dx Dy Dz 1788 Total -0.00006048 3.74401881 -0.00000937 1789 Core 0.00217339 205.07009315 0.00129867 1790 Electron -0.00223387 -201.32607435 -0.00130804 1791 Back ground 0.00000000 -0.00000000 0.00000000 1792 1793*********************************************************** 1794*********************************************************** 1795 xyz-coordinates (Ang) and forces (Hartree/Bohr) 1796*********************************************************** 1797*********************************************************** 1798 1799<coordinates.forces 1800 6 1801 1 O 0.00006 0.04713 -0.00000 -0.000000602940 0.000032663916 0.000000003443 1802 2 H 0.76137 0.65004 0.00000 -0.000005097238 -0.000005833984 0.000000008055 1803 3 H -0.76129 0.64999 0.00000 0.000002551087 -0.000003715927 0.000000007754 1804 4 O 0.00000 4.98899 0.00003 -0.000000208546 -0.000018471004 -0.000000441154 1805 5 H -0.00000 5.58885 0.76342 0.000000009316 -0.000027213855 -0.000006215637 1806 6 H -0.00000 5.58883 -0.76336 0.000000008855 -0.000026501601 0.000005274855 1807coordinates.forces> 1808 1809*********************************************************** 1810*********************************************************** 1811 Fractional coordinates of the final structure 1812*********************************************************** 1813*********************************************************** 1814 1815 1 O 0.00000600447464 0.00316953877401 0.99999999247682 1816 2 H 0.07680550779885 0.04371646553073 0.00000009905902 1817 3 H 0.92320303207019 0.04371314909874 0.00000011177878 1818 4 O 0.00000018282251 0.33551938761811 0.00000349708559 1819 5 H 0.99999999434607 0.37586107808166 0.07701185345128 1820 6 H 0.99999998806171 0.37586020183916 0.92299427337554 1821 1822*********************************************************** 1823*********************************************************** 1824 Computational Time (second) 1825*********************************************************** 1826*********************************************************** 1827 1828 Elapsed.Time. 62.795 1829 1830 Min_ID Min_Time Max_ID Max_Time 1831 Total Computational Time = 5 62.669 0 62.795 1832 readfile = 5 4.374 8 4.383 1833 truncation = 0 0.000 0 0.000 1834 MD_pac = 0 0.010 13 0.012 1835 OutData = 14 0.000 0 0.117 1836 DFT = 1 55.951 8 56.172 1837 1838*** In DFT *** 1839 1840 Set_OLP_Kin = 12 1.595 1 2.785 1841 Set_Nonlocal = 1 1.960 12 3.365 1842 Set_ProExpn_VNA = 8 5.057 0 5.461 1843 Set_Hamiltonian = 4 21.373 14 21.428 1844 Poisson = 3 1.858 8 1.861 1845 Diagonalization = 3 0.539 4 0.565 1846 Mixing_DM = 3 0.034 10 0.035 1847 Force = 7 7.172 8 7.172 1848 Total_Energy = 3 3.390 0 3.393 1849 Set_Aden_Grid = 4 0.585 8 0.995 1850 Set_Orbitals_Grid = 11 0.000 1 2.326 1851 Set_Density_Grid = 15 7.399 9 7.999 1852 RestartFileDFT = 11 0.272 6 2.398 1853 Mulliken_Charge = 1 0.026 12 0.027 1854 FFT(2D)_Density = 0 0.000 0 0.000 1855 Others = 2 0.198 13 2.621 1856